Incorporating green and sustainable remediation analysis in coal combustion residuals (CCR) surface impoundment closure decision making

In response to new coal combustion residuals (CCR) disposal regulations, many coal‐fired utilities have closed existing unlined surface impoundments (SIs) that were traditionally used for disposal of CCR. The two primary closure options are closure‐in‐place (CIP), which involves dewatering and capping, and closure‐by‐removal (CBR), which includes excavation, transportation, and disposal of the CCR into a lined landfill. This article provides a methodology and a case study of how green and sustainable remediation concepts, including accounting for the life cycle environmental footprints and the physical risks to workers and community members, can be incorporated into the closure decision‐making process. The environmental impacts, occupational risks, and traffic‐related fatalities and injuries to workers and community members were calculated and compared for closure alternatives at a hypothetical site. The results demonstrated that the adverse impacts of the CBR option were significantly greater than those of the CIP option with respect to the analyzed impact pathways.     

Proposing of new building scheme and composite towards global warming mitigation for Malaysia

The building sector has been regarded as a potential sector where there is large capacity to reduce the climate change effect. This study has proposed solutions to mitigate environmental impacts and achieve low CO₂ emission from residential sector. Therefore, full life cycle assessment (LCA) has been run to assess the CO₂ emission and its effect on the atmosphere and climate change. Based on the result, timber scheme is the best choice due to releasing less CO₂ emissions to the atmosphere. However, house builders in Malaysia have almost completely neglected timber as a building material, with timber use as building components reduced to 5%. In this study, LCA Software was used to assess CO₂ emissions from different wall construction. The alternative building scheme has been made by reinforce steel stud, wooden beam and timber wall (S8) to improve the scheme deficiency while releasing less CO₂ emissions compared to other schemes. Therefore, S8 has a decreased CO₂ effect by 85% less than precast concrete frame and 90% less than brick over their lifetime. (S8) increased the load bearing compared to conventional timber beam. Thus, new scheme S8 could be replaced by current scheme and promote more adjustable scheme for Malaysian housing.     

Proximate composition and mineral contents in the body wall of two species of sea cucumber from Oman Sea

The proximate composition and mineral contents of Stichopus horrens and Holothuria arenicola from Chabahar Bay were analyzed and investigated. During the present study, we aimed to demonstrate the nutritive value. The approximate percent composition of moisture, protein, fat, and ash were 92.8, 3.47, 0.4, and 3.33% in S. horrens and 93, 4.4, 0.6, and 2% in H. arenicola, respectively. Atomic absorption spectrophotometry of the ashes indicated the body wall of two species of sea cucumbers contained higher amounts of both macro minerals (92.5 mg/100 g Mg in S. horrens and 115 mg/100 g Mg in H. arenicola; 106.25 mg/100 g Ca in S. horrens and 83.25 mg/100 g Ca in H. arenicola) and trace elements (521.781 mg/100 g Fe in S. horrens; 60.354 mg/100 g Fe in H. arenicola, and 0.096 mg/100 g Zn in S. horrens; 0.04 mg/100 g Zn in H. arenicola). For both species, there were high content of protein and essential mineral. Also, they have low content of fat in the body wall of two species in the experiment.     

Phyto-management of Cr-contaminated soils by sunflower hybrids: physiological and biochemical response and metal extractability under Cr stress

Environmental Science and Pollution Research - Chromium (Cr) is a biologically non-essential, carcinogenic and toxic heavy metal. The cultivation of Cr-tolerant genotypes seems the most favorable...     

Land-use change and its socio-environmental impact in Eastern Ethiopia’s highland

The Alemaya district (Eastern Ethiopian highlands) is characterized by undulating physiographic features with arid, semi-arid, and humid climatic conditions. This study evaluated socio-environmental changes in land use and land cover during 1985–2011. Screen digitization on remotely sensed data (i.e., Landsat images from 1985 to 2011) was performed to produce 10 classes of land use and land cover. Then, final land-use maps were prepared using a geographic information system following field verification and accuracy assessment. The drying of water bodies, including the prominent lakes Alemaya, Adele, and Tinike, had been the most important environmental change observed. Degraded land, marsh, perennial cropland, and residential areas increased by 37, 438, 42, and 190 %, respectively, whereas grassland, plantation, shrubland, and temporal cropland decreased by 64, 11, 63, and 29 %, respectively. The increase in land degradation (+37 %), the other major observed problem, has made large areas unsuitable for agriculture and has reduced crop productivity. These land-use and land-cover changes have affected both the environment and the livelihoods of local residents; especially the issue related to land degradation requires urgent attention.     

Microwave irradiation and citric acid assisted seed germination and phytoextraction of nickel (Ni) by <Emphasis Type="Italic">Brassica napus</Emphasis> L.: morpho-physiological and biochemical alterations under Ni stress

The complex bio-geochemistry of soil allows pollutant to persist for a longer period of time which further decreased the fertility and natural composition of land. Nickel, an inorganic pollutant, coming from a wide range of industrial and manufacturing units possesses serious threat to soil degradation and crop productivity around the world. The present study was carried to evaluate the combined role of microwave irradiation (MR) and citric acid (CA) on the phytoextraction potential of Brassica napus L. under Ni stress. An initial seed germination test was conducted to select effective time scale of MR exposure. Highest seed germination was observed at exposure of 2.45 GHz frequency for 30 s. Healthy seeds of B. napus L. genotype Faisal Canola (RBN-03060) treated with MR at 2.45 GHz for 30 s were sown in plastic pots filled with 5 kg of soil. Nickel and CA applied exogenously in solution form with different combinations to both MR-treated and untreated B. napus plants. The MR-treated plants showed higher growth, biomass, photosynthetic pigments (Chl a, b, total, and carotenoids) and activities of antioxidant enzymes (SOD, POD, APX, CAT) as compared to untreated plants who showed higher reactive oxygen species (MDA, H₂O₂) and electrolyte leakage. Increasing Ni concentration significantly decreased the physiological and biochemical attributes of B. napus both in MR-treated and untreated plants. The addition of CA alleviated Ni-induced toxic effects in both MR-treated and untreated plants by improving antioxidant defense system. The degree of Ni stress mitigation was higher in MR-treated plants. The Ni concentration was higher in root, stem, and leaves of MR-treated plants under CA application as compared to untreated plants. The present study concluded that seeds treated with MR before sowing showed higher accumulation and concentration of Ni from soil, and this phenomenon boosted with the application of CA.     

Assessment of tap water quality and corrosion scales from the selected distribution systems in northern Pakistan

Corrosion deposits formed within drinking water distribution systems deteriorate drinking water quality and resultantly cause public health consequences. In the present study, an attempt was made to investigate the concurrent conditions of corrosion scales and the drinking water quality in selected water supply schemes (WSS) in districts Chitral, Peshawar, and Abbottabad, northern Pakistan. Characterization analyses of the corrosion by-products revealed the presence of α-FeOOH, γ-FeOOH, Fe₃O₄, and SiO₂ as major constituents with different proportions. The constituents of all the representative XRD peaks of Peshawar WSS were found insignificant as compared to other WSS, and the reason could be the variation of source water quality. Well-crystallized particles in SEM images indicated the formation of dense oxide layer on corrosion by-products. A wider asymmetric vibration peak of SiO₂ appeared only in Chitral and Abbottabad WSS, which demonstrated higher siltation in the water source. One-way ANOVA analysis showed significant variations in pH, turbidity, TDS, K, Mg, PO₄, Cl, and SO₄ values, which revealed that these parameters differently contributed to the source water quality. Findings from this study suggested the implementation of proper corrosion prevention measures and the establishment of international collaboration for best corrosion practices, expertise, and developing standards.     

Assessment of trace metal concentrations in muscle tissue of certain commercially available fish species from Kayseri,Turkey

Regular consumption of fish has been widely recommended by health authorities. However, it is known that some species accumulate high levels of contaminants including heavy metals (e.g., Hg, Cd, Pb, and As). In this study, Cu, Pb, Co, Ni, Cr, Mn, Cd, and Fe were determined in the muscle tissue of 11 commercially available fish species (Sparus auratus, Dicentrarchus labrax, Mullus barbatus, Belone belone, Psetta maxima, Epinephelus aeneus, Salmothymus, Soleidae, Pomatomus saltatrix, Engraulis encrasicolus, and Sarda sarda) supplied from retailers in Kayseri, Turkey. Determinations were carried out by flame atomic absorption spectrometry after the wet digestion method. The average metal concentrations of the 11 species were determined in the range of 0.54–1.79, 0.82–1.40, 2.38–4.54, 1.23–3.67, 5.01–5.97, 0.77–3.59, 0.48–1.06, and 5.05–122.8 μg/g wet weight for Cu, Pb, Co, Ni, Cr, Mn, Cd, and Fe, respectively. The permissible tolerable daily intake (PTDI) and calculated daily intake (CDI) values were compared, and the calculated daily intake values of the samples were found to be below the established values. Correlations between the metal contents in samples were investigated by performing correlation tests with SPSS 13.0 for windows.